Using rice husks for making pesticide


This research was done at Franciscan seminary Maua by two students 'Francis Protas Shirima' and 'Newton Norbert Mshanga' assisted by thier Physics and Chemistry teacher 'Faustin Sagenge' in 2013.

Introduction:
It has been observed that different cereal crops like maize, beans and soghum are destroyed by pests like weevils, but not rice. What if someone decides to remove the hard coating{husks} from rice, pure rice are also destroyed easier by weevils? Does the husk only prevent the attack of pesticides to rice? The study on the chemical content present in husks suggests the presence of phosphorus, potassium, and silicon. Pesticides can be made from phosphorus and other elements. When pesticides made from phosphorus is needed; the source of phosphorus should be obtained, and mainly is obtained from vegetations that grows in mad water that enable them to absorb it from the soil. It can be proved for its presence by addition of P.O.P to phosphorus expected sample followed by sulfuric acid and finally addition of sodium hydroxide. The faint pink color confirms the presence of phosphorus. Different theories explained on how phosphorus is extracted or the presence of phosphorus in rice husks. Good and less toxic pesticides could be made by using rice husks ashes modifying them into potassium phosphide.

Materials:
Testing of the effectiveness of the pesticide : This was done by using maize grains to be stored as well as growing of maize in the selected school area. Storing of maize grains in a store

Research procedures:
7 tins un-affected school maize grains were taken and divided into two portions each with 3.5 tins of maize grains Each portion was placed in a separate sack In one sack a half tin of prepared rice husks ashes were introduced In the other portion no ashes were introduced Then in each about 30 maize weevils obtained from a school store were introduced and sacks left while close for 3 months while observing the destruction of maize after every 25 days The record on how destruction of maize grains were taken after every 15 days.

Step1: Making of rice husks
Procedures: Rice husks were taken (two tins of rice husks0 and burned in air The burned husks (ashes) were collected and stored in a well prepared sack

Step 2: Testing for presence of phosphorus in husks:
Procedures: little amount of well prepared ashes (two tea spoons) were taken and placed in a conical flask. four (4) cm3 of p.o.p were added into a conical flask 10cm3 of dilute sulphuric acid were added into the mixture finally 10cm3 of aqueous sodium hydroxide were added into the mixture; and the faint pink colour observed

Step 3: Extracting/preparing of phosphorus from ashes
Procedures: ashes (rice husks ashes) were taken and mixed with coke in a Pyrex large conical boiling flask Heating process to about 10 minutes was done while allowing the gas to escape from the flask Removal of top floating layer was done (slag) A white liquid was seen to condense and collected. This is white phosphorus. No of days

Results:

For step 1:
When rice husks were burnt in air, black residues {ashes}were formed; and colourless gases were evolved. This agreed with Lambert & Holderness{1961:477},who explained that “burning of organic matter either from bones or minerals phosphates leaves the residue containing calcium phosphate{ }.for that case our rice husks containing potassium phosphate and carbon, the gases evolved were carbon dioxide and the residue remained were potassium phosphate that can be used as pesticide.

For step 2:
When P.O.P was used followed by addition of sulphuric acid and finally sodium hydroxide, faint pink color was formed. This shows that rice husks contains phosphorus.

For step 3:
When little amount of heat was supplied so as to heat the mixture of ashes, sand and coke no clear product was formed except the colorless gas that turned lime water into milk. When much heat was supplied ,the slug was formed at the top that floats; Also the white destils of phosphorus was formed that changed to white solid. Also a gas [colorless] was evolved ,it was carbon monoxide gas. Materials:

Conclusions:
According to the results, it is proved that rice husks contains potassium and phosphorus elements, These elements are used by plants for two different purposes, either as fertilizer or as pesticides. The process of preventing maize grains from being destroyed by pests, proved that phosphorous and potassium can be used to either kill the pests or expel the pests. This agreed with Ngungi D.Nel.al(1978:81), who argued on how to make pesticide found in form of fumigant is phosphine; and phosphine contains phosphorous and hydrogen ions, through it is too toxic. R